are classified in the Class 1 hazard class. the date on which the dangerous goods were classified. What safety marks are required on a large means of containment (capacity 450L or more)? Who has responsibilities for dangerous goods safety marks? Generally, if the shipment includes dangerous goods in Class 7, Radioactive Materials, then two labels are required on the small means of containment. More than one subsidiary class is possible. 391-3-17-.06 - Rule 391-3-17-.06 - Transportation of Radioactive Material, 410 Ind. For example, the shipping name for a mixture that consists of 80% gasoline and 20% diesel will be: FLAMMABLE LIQUID, N.O.S. They are preferred in the following order: If you cannot find a good match in 1, you move to 2, 3 and 4 by order. Figure 1: Label and placard (Image from Transport Canada). Dangerous Goods of Class4.2, Packing Group III, not listed above, Magnesium powder or Magnesium alloys, powder, Dangerous Goods of Class4.3, Packing Groups I, not listed above, Aluminum smelting by-products or Aluminum remelting by-products, Phosphorus pentasulphide, free from yellow and white phosphorus, Dangerous Goods of Class4.3, Packing Groups II, not listed above, Calcium cyanamide, with more than 0.1% Calcium carbide, Ferrosilicon, with 30% or more but less than 90% silicon, Magnesium granules, coated, particle size not less than 149mm, Dangerous Goods of Class4.3, Packing Group III, not listed above, Ammonium nitrate, liquid, hot concentrated solution, Hydrogen peroxide, stabilized or Hydrogen peroxide, aqueous solutions, stabilized, with more than 60% hydrogen peroxide, Dangerous Goods of Class5.1, Packing Group I, not listed above, Calcium hypochlorite, hydrated or Calcium hypochlorite, hydrated mixture, with not less than 5.5% but not more than 16% water, Dichloroisocyanuric acid, dry or Dichloroisocyanuric acid salts, Hydrogen peroxide, aqueous solution, with more than 40% but not more than 60% hydrogen peroxide, stabilized, as necessary, Hydrogen peroxide, aqueous solution, with not less than 20% but not more than 40% hydrogen peroxide, stabilized, as necessary, Potassium nitrate and sodium nitrite mixture, Dangerous Goods of Class5.1, Packing Group II, not listed above, Dangerous Goods of Class5.1, Packing GroupII, Solids, not listed above, having no subsidiary class other than Class9, Dangerous Goods of Class5.1, Packing GroupIII, Liquids, Dangerous Goods of Class5.1, Packing GroupIII, Solids, Dangerous Goods of Class5.2, Packing GroupI, Dangerous Goods of Class5.2, Packing GroupII, Dangerous Goods of Class5.2, Packing GroupIII, Hydrocyanic acid, aqueous solution, with not more than 20% hydrogen cyanide, Hydrogen cyanide, solution in alcohol, with not more than 45 percent hydrogen cyanide, Hydrogen cyanide, stabilized, containing less than 3% water, Methyl bromide and ethylene dibromide mixture, liquid, Organochlorine pesticide, liquid, toxic, flammable, flashpoint not less than 23C (73F), Toxic by inhalation, liquid, n.o.s., with an LC, Toxic by inhalation, liquid, flammable, n.o.s., with an LC, Toxic by inhalation, liquid, water reactive, n.o.s., with an LC, Toxic by inhalation, liquid, oxidizing, n.o.s., with an LC, Toxic by inhalation, liquid, corrosive, n.o.s., with an LC, Dangerous Goods of Class6.1, Packing GroupI, Liquids, not listed above, Dangerous Goods of Class6.1, Packing GroupI, Solids, not listed above, Dangerous Goods of Class6.1, Packing GroupII, Liquids, not listed above, Dangerous Goods of Class6.1, Packing GroupII, Solids, not listed above, Dangerous Goods of Class6.1, Packing GroupIII, Liquids, not listed above, Dangerous Goods of Class6.1, Packing GroupIII, Solids, not listed above, Dangerous Goods of Class6.1, Packing GroupIII, not listed above, with a subsidiary classification other than 9, Chlorosulphonic acid, with or without sulphur trioxide, Hydrazine, aqueous solution, with more than 37% hydrazine, by mass, Hydrazine, aqueous solution, flammable with more than 37% hydrazine, by mass, Hydrofluoric acid and sulphuric acid mixture, Hydrofluoric acid solution, more than 60% hydrogen fluoride, Nitrating acid mixtures, more than 50% nitric acid, Nitric acid, other than red fuming, with more than 70% nitric acid, Sulphuric acid, fuming, greater than or equal to 30% free sulphur trioxide, Sulphuric acid, fuming, less than 30% free sulphur trioxide, Dangerous Goods of Class8, Packing GroupI, not listed above, Battery fluid, acid or Sulphuric acid, with not more than 51% acid, Formic acid, with more than 85% acid by mass, Hydrofluoric acid solution, not more than 60% hydrogen fluoride, Nitrating acid mixtures, not more than 50% nitric acid, Nitric acid, other than red fuming, with not more than 70% nitric acid, Dangerous Goods of Class8, Packing GroupII, Liquids, not listed above, Dangerous Goods of Class8, Packing GroupII, Solids, not listed above, Dangerous Goods of Class8, Packing GroupIII, Liquids, not listed above, Dangerous Goods of Class 8, Packing Group III, Solids, not listed above, Dangerous Goods of Class9, Packing GroupI, Liquids, Dangerous Goods of Class 9, Packing Group I, Solids, Blue asbestos (crocidolite) or Brown asbestos (amosite, mysorite), Dangerous Goods of Class9, Packing GroupII, Liquids, not listed above, Dangerous Goods of Class 9, Packing Group II, Solids, not listed above. How many placards are required on a large means of containment? The primary class is the class of dangerous goods that takes precedence over any other class. Transport Canada is closely monitoring the COVID-19 situation. 13 020 - 13-020 - ADVANCE NOTIFICATION OF TRANSPORT OF NUCLEAR WASTE, 10A NCAC 15 .0346 - 10A NCAC 15 .0346 - PREPARATION OF RADIOACTIVE MATERIAL FOR TRANSPORT. This mark is required when shipments meet the limited quantity exemption, and must be displayed on one side of a means of containment. You may also find an expert in CSP business directory below. The size (i.e., capacity) of the means of containment itself also determines whether a label or placard is required. Dangerous Goods of Class4.1, Packing Group II, not listed above, Magnesium or Magnesium alloys, with more than 50% magnesium, in pellets, turnings or ribbons, Naphthalene, crude or Naphthalene, refined, Titanium sponge granules or Titanium sponge powders, Dangerous Goods of Class4.1, Packing GroupIII, not listed above, Organometallic substance, solid, pyrophoric, water-reactive, Organometallic substance, liquid, pyrophoric, water-reactive, Phosphorus, white or Phosphorus, yellow, dry or Phosphorous, yellow, in solution or Phosphorous, yellow, underwater, Dangerous Goods of Class4.2, Packing Group I, not listed above, Potassium sulphide, anhydrous or Potassium sulphide, with less than 30% water of crystallization. as appropriate. http://www.unece.org/fileadmin/DAM/trans/danger/publi/unrec/rev16/English/02E_Part2.pdf. %PDF-1.5 % Services Main Page. (iv) for dangerous goods with a primary class of Class 1, Explosives, the compatibility group letter following the primary class. In this case, the product is not TDG regulated and the product does not need to comply with the TDG Regulations. Other dangerous goods safety marks that may be required for a shipment of dangerous goods are summarized in Table 2 below. Danger placard (instead of the individual hazard class placards) may be displayed when only the following dangerous goods are present in the shipment are classified in: Class 2 gases shipment in combination of two or more cylinders that have a combined capacity exceeding 450 L such that: The combination of cylinders may be placarded as one large means of containment. If the product is not listed by specific name in Schedule 1 or 3, check if it meets any of the criteria for the hazard classes in Part 2 - Classification. Transportation of Dangerous Goods (TDG) - Classification, All Products and It can also negatively affect reproductive health. UN Number This column gives the UN number assigned to the dangerous goods under the UN system. You need to choose a UN number (usually, 4 digits) and a proper shipping name from Dangerous Goods List that can most accurately describe your dangerous goods. See Section 2.5. (e) Except for those materials in the UN Recommendations, the ICAO Technical Instructions, or the IMDG Code (IBR, see 171.7 of this subchapter), a material that is not a hazardous material according to this subchapter may not be offered for transportation or transported when its description on a shipping paper includes a hazard class or an identification number specified in the 172.101 Table. "R}~Q:~pgg'"l/O:OV~ @zo7g;)K;=d'}z8}7w7?Iuw?w~ikK^^'d4k;g_u_LOC6($uiz["Dw#b{ogw~0B"ty'{~Oi"v?`"DqXmImPiww#R{;?j}J3]0{ ?>]|YlbE#SsBsz/E":}NCg7ON2P5N}s/w?9LO?zZ^/1BWu~N"r~!P;1FAS*:hzQHo _+3l3E6FAsmH}]fwcxoCcbb,!7cTvt{o&h: foC"uF2c;&4m;vx?=8 ga ` !%6M`Wn-@lM;#={CSaW+r:&|gB7/ndJlXqFxs1}n]N:=jd#]5$b{9NF">OL_7!y;3~*cQlCek4o6 eeGn:9P_mO}W'^q7{X,V{TFi8Qj eg/od{QVg{*Ky3n_0ht vv@9g;OkRz~w}79!^C:[7C .{;T/tUOB9x|]\;Q7W{!~uhM See Section 1.17 in the TDG Regulations. Can I use a UN number that is not included in the Canadian TDG Regulations? The subsidiary hazard class or division number is not required to be entered when a corresponding subsidiary hazard label is not required. 120.790 - 120.790 - Advance Notification of Shipment of Nuclear Waste, 180 Neb. A substance, mixture, or article that is a marine pollutant and does not meet the classification criteria for inclusion in any other hazard class shall be declared under either UN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, n.o.s. EDT. As per subsection 11.1(1) of the TDG Regulations, the IMDG Code must be consulted for international transport by ship. (iii) the primary class, which may be shown as a number only or under the heading Class or Classe or following the word Class or Classe. This mark is displayed on small means of containment filled with infectious substances that are assigned to UN3373, Biological Substance Category B. It can be either a tag or a fixed display device (white board or a piece of paper) that will be updated every time a dangerous good is removed or added (Section 4.10.2 in the TDG Regulations). will be unavailable during this time. For pure chemical substances or well-defined articles, it is easy to choose UN numbers and proper shipping names. There are 4 types of entries consisting of UN numbers and proper shipping names in the How do I report the classification or shipping description on a shipping document? Image from Alberta EDGE (Environmental and Dangerous Goods Emergencies), Alberta Transportation. View Past Newsletter, http://www.unece.org/fileadmin/DAM/trans/danger/publi/adr/adr2011/English/Part3.pdf, http://www.phmsa.dot.gov/filename/Marine_Pollutant_Guidance.pdf, Biocides and Biocidal Product Regulations, Example: UN 1133 ADHESIVES containing flammable liquids; UN 1263, PAINT, Example: UN 1987 ALCOHOLS, N.O.S. Who is responsible for classifying a dangerous good? See Section 4.23 of Part 4 in the TDG Regulations. Used to display the UN number on a large means of containment (greater than 450 L) when the UN number is not included in the hazard class placard. CCOHS is not liable for any loss, claim, or demand arising directly or indirectly from any use or reliance upon the information. Example: UN 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. If the product's name is listed in Schedule 1 or you located it by using the listed UN Number in Schedule 3, use the shipping name and its corresponding data (UN number, class, packing group/category) from that row. The following provisions also apply: (i) For empty uncleaned packaging, only the number and type of packaging must be shown; (ii) For chemical kits and first aid kits, the total net mass of hazardous materials must be shown. Products and Although there are different degrees of separation of dangerous goods UN-2 WebClassification of dangerous goods is broken down into nine classes according to the type of danger materials or items present, click on a class to read more details; 1. Classification is normally done by (or in consultation with): If you are the manufacturer of the product, the product must be tested according to Part 2 of TDG Regulations. Subscribe to Free Newsletter What is its predominant hazard substance and primary hazard? Figure 2: Safety marks on a small means of containment such as a package Note 1: The orientation marks for liquids are optional for road transport, but mandatory for air transport. Special Provisions This column gives the special provisions that apply to the dangerous goods. ), code or number for a particular hazard (e.g., 1- Explosive, 2 - Gases, 3 - Flammables), Provide quick identification of the dangerous goods in an emergency (e.g., release of dangerous goods during an incident), Communicate the nature and degree of the danger, Quickly determine if dangerous goods in a mixed load are incompatible, is determined to be a dangerous good under the TDG Regulations, and, displayed against a background of contrasting colour, made of durable, weather-resistant material that will resist coming detached or fade, Select the correct label(s) for each small means of containment (e.g., drum, package, overpack), Make sure that each small means of containment (e.g., package or container) of dangerous goods is properly labelled and marked, Select the correct placards and other safety marks for each large means of containment (e.g., tanker), Display the placards and other safety marks, or provide the appropriate placards to the carrier (when the means of containment or means of transport belongs to the carrier), Confirm that the safety marks are correct, Make sure the safety marks are displayed and remain displayed during transport, Replace safety marks when during transport they are stolen, lost, or defaced, Provide and display appropriate safety marks when the contents of the shipment change (e.g., new consignments are loaded on the means of transport), Remove or cover safety marks when the dangerous good is no longer present. (contains Xylene and Benzene), 3, II. a document that explains how the dangerous goods were classified. ?O.Q\tF,"V4Iuu8jhb7ew?NI ~eS^lsEU_{\3>e; F]u:MvF7Bz3Jz;O>tzw5qy:!&|]&$fG6F`B@a'\` Eno14}tQ`?K4%1nFh,D_Qg4f>~j $7NH s:o~P;v4fRd%r{6|;>v&K >Z!O~X}u!wv=@~0}$vN=. This document may be: The proof of classification must include the following information: The TDG Directorate keeps alist of laboratoriesthat provide dangerous goods analysis and classification. For example: UN 1993, Flammable liquids, n.o.s. This sign must be displayed at or next to each entry way of the large means of containment (greater than 450 L) when the containment is fumigated with a dangerous good. Flammable Gases 3. WebMercury Marineis a marine enginedivision of Brunswick Corporationheadquartered in Fond du Lac, Wisconsin. How do I determine the identification number / UN Number? For example, if you have a product for which you determined that the shipping name will be FLAMMABLE LIQUID, N.O.S. : M141-1LB; M141-6LB Synonyms Colloidal mercury; Hydrargyrum; Metallic mercuryRecommended Use For transport from the United States into Canada by road vehicle or railway vehicle, the shipping name used must be one that is recognized in Schedule 1 of the TDG Regulations or in the UN Recommendations. Please check if any of these measures apply to you. How do I assign Categories A and B for the infectious substances? If a mixture or solution is composed of a single predominant substance mentioned in the Dangerous Goods List and one or more substances not subject to DG classification, the mixture shall be assigned to the Proper Shipping Name of the predominant substance mentioned in the Dangerous Goods List by adding the qualifying words "MIXTURE" or "SOLUTION" unless: Example: UN 1090 ACETONE SOLUTION, or UN 1090 ACETONE 75% SOLUTION. If a small means of containment is placed inside another, and the outer container is not opened during loading, transport or unloading, the label is required only on the outer small means of containment. Mercury is a naturally-occurring chemical element found in rock in the earth's crust, including in deposits of coal. What is the purpose of dangerous goods safety marks? Only required when a marine pollutant is being transported in a means of containment on a vessel. This placard is not mandatory, but it is permitted on a large means of containment (greater than 450 L) instead of any other placard when the containment has: - one or more dangerous goods that require different hazard class placards, - the dangerous goods are contained in two or more small means of containment, AND - the shipment consists of only the following dangerous goods classified in: NOTE: The TDG Regulations has specified circumstances when this placard is not allowed to be used. In this article, we will share with you some rules you need to follow when choosing UN numbers and proper shipping names. For example, UN3518 ADSORBED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S. has three hazard classes assigned to it in Column 3 of Schedule 1. This communication is accomplished by the: Note that the difference between labels and placards is their size. You can ;imX'1r9-Ttomh1!u~cSyK,v=d+2Cl>AmY\t%v|a&H%dl>; CbtgspL4nj(|c24O?DY_L[;!/aw=yAcC)fMZEnti ]~Mal};jv|y{D}odxh*ap-UDw,EY"h7!G07znrn83Qa=Xre:NWMg]3|u`gho7Ay0Cgh!7tf16+OIXe"m>GNkhhu&.7f{,M` =WaJ`I{W2O_eBX;96$ljWt8 There may be occasions when several different shipping names can be used. The classification or shipping description is reported in the following order as per Part 3.5: (ii) the shipping name and, immediately after the shipping name unless it is already part of it, (a) for dangerous goods that are subject to special provision 16, the technical name, in parentheses, of at least one of the most dangerous substances that predominantly contributes to the hazard or hazards posed by the dangerous goods, and. (1) The total quantity of the material covered by one description must appear before or after, or both before and after, the description required and authorized by this subpart. That legal outcome opened the door to hire a new design and construction team to finish the North Course. Definition for a solution When the ingredients in a mixture are completely dissolved. Specific chemical name (e.g., acetone, sulfuric acid, etc. (i) The words Class or Division may be included preceding the primary and subsidiary hazard class or division numbers. (gasoline). Although a consignor may also use the classification of the manufacturer or a previous consignor, the consignor is still responsible for making sure the classification is correct, and for making a proof of classification available to the Minister.

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